1.An AIE active acidochromic pyrimidine-functionalized two-in-one fluorescent probe for selective relay detection of Al³⁺/Zn²⁺ and PPi with various detection applications.
O. Anitha, J. Aiswarya, T. Thiruppathiraja, S. Lakshmipathi J. G. Malecki and B. Murugesapandian*
New J. Chem., 47, 18461 (2023).

2.Diethylaminophenol appended pyrimidine bis hydrazone for the sequential detection of Al³⁺ and PPi ions,
O. Anitha, T. Thiruppathiraja, S. Lakshmipathi and B. Murugesapandian*
Spectrochim. Acta A: Mol. and Biomol. Spectrosc., 302, 123077 (2023).

3. Visualization of latent fingerprints using an AIE-active unsymmetrical azine: 2-Naphthol-pyrrole acrylate conjugate and its fluorescent sensing of Cu²⁺ and S²⁻ ions, smartphone and logic gate applications,
B. Tharmalingam, O. Anitha, J. Aiswarya, T. Thiruppathiraja, S. Lakshmipathi and B. Murugesapandian* 
J. Photochem. Photobiol. A, 442, 114757 (2023)

4. A unique methanol responsiveness, AIE, acidochromism and mechanofluorochromic features of flexible ethylenediamine bridged rhodamine B-diethylamino hydroxycoumarin conjugate,
M. Mathivanan, B. Tharmalingam, O. Anitha,T. Thiruppathiraja, S. Lakshmipathi, J. G. Malecki  and B. Murugesapandian
J. Mol. Liq., 382, 121845 (2023).

5. Multi-stimuli responsiveness of pyrimidine bishydrazone: AIE, tuneable luminescence, white light emission, mechanochromism, acidochromism and its anticounterfeiting applications,
O. Anitha, M. Mathivanan, B. Tharmalingam, T. Thiruppathiraja, S. Ghorai, R. Natarajan, V. Thiagarajan, S. Lakshmipathi and B. Murugesapandian*
Dyes Pigm., 212, 111091 (2023).

6 A new 7-(diethylamino)coumarin and 4-(diethylamino)phenol appended unsymmetrical thiocarbohydrazone: Detection of moisture in organic solvent and sequential fluorimetric detection of Cu²⁺ ions and cysteine,
K. Santhiya, M. Mathivanan, B. Tharmalingam, O. Anitha, S. Ghorai, R. Natarajan and B. Murugesapandian* 
J. Photochem. Photobiol. A, 432, 114105 (2022).

7. Substitution dependent multi-color AIE behavior and ESIPT active A-D-A type triphenylamine supported bis unsymmetrical azine derivatives and their antibacterial activity,
M. Mathivanan and B. Murugesapandian* 
Dyes Pigm., 203, 110367 (2022).

8. Nitrogen rich triaminoguanidine-pyrrole conjugate as supramolecular synthon for the construction of charge-assisted hydrogen bonded network with various carboxylic acids,
B. Tharmalingam, M.Mathivanan, O. Anitha, W. Kaminsky and B. Murugesapandian* 
J. Solid State Chem., 305, 122637 (2022).

9. All-in-one type ESIPT-active multi-stimuli responsive 7-diethylamino-4-hydroxycoumarin-rhodamine B hydrazone as molecular switches and the reversible photochromic features of its zinc ensemble.
M. Mathivanan, B. Tharmalingam, O. Anitha, C.H. Lin, V. Thiagarajan,  B. Murugesapandian*
Materials Chemistry Frontiers, 5, 8183-8196 (2021).

10. A new 7-diethylamino-4-hydroxycoumarin based reversible colorimetric/fluorometric probe for sequential detection of Al³⁺/PPi and its potential use in biodetection and bioimaging applications,
M.Mathivanan, B. Tharmalingam, T.Devaraj, A. Murugan, C.-H. Lin, M.Jothi, and B. Murugesapandian* 
New J. Chem., 45, 6067-6079 (2021).

11. Multifunctional behavior of bis-acylhydrazone: Real-time detection of moisture in organic solvents, halochromism and aggregation induced emission,
K. Santhiya, S. K. Sem, R. Natarajan, and B. Murugesapandian*
Dyes Pigm., 185, 108891 (2021).

12. Development of C₃ symmetric triaminoguanidine-2-naphthol conjugate: Aggregation induced emission, colorimetric and turn-off fluorimetric detection of Co²⁺ ion, smartphone and real sample applications,
B. Tharmalingam, M. Mathivanan, O. Anitha, and B. Murugesapandian*
J. Photochem. Photobiol. A, 406, 112983 (2021).

12. Electronically induced steric clash: synthesis of NMe₂-modified β-diketiminate-supported boron difluoride compounds,
B. Murugesapandian, R. Ganguly, P.Lee, M. Petkovic, J. Clyburne, D. Vidovic,  Aust. J. Chem., 73(12) 1219-1225 (2020).

14. C₃-symmetric triaminoguanidine based colorimetric and fluorometricchemosensor: sequential detection of Zn2+/PPi, its RGB performance for detection of Zn²⁺ ion and construction of IMPLICATION logic gate,
B. Tharmalingam, M. Mathivanan and B. Murugesapandian*
Spectrochim. Acta A: Mol. and Biomol. Spectrosc., 242, 118749 (2020).

15. Simple C₃-symmetric triaminoguanidine-triphenylamine conjugate as an efficient colorimetric sensor for Cu(II) and fluorescent sensor for Fe(III) ions.
M. Mathivanan, B. Tharmalingam, K.S. Mani, V. Thiagarajan and B. Murugesapandian*
Spectrochim. Acta A: Mol. and Biomol. Spectrosc., 234, 118235 (2020).

16. Selective detection of pyrophosphate anion by zinc ensemble of C₃-symmetric triaminoguanidine-pyrrole conjugate and its biosensing applications,
B. Tharmalingam, M.Mathivanan, K.S. Mani, W. Kaminsky, A. Raghunath, M. Jothi, E. Perumal, B. Murugesapandian*
Anal. Chim. Acta, 1103, 192-201 (2020).

17. ESIPT active multi-color aggregation induced emission features of triphenylamine-salicylaldehyde based unsymmetrical azinefamily.
M. Mathivanan, B. Tharmalingam, C.H. Lin, B. V. Pandiyan, V. Thiagarajan and B. Murugesapandian*  
CrystEngComm, 22, 213-228 (2020).

18. Star-shaped ESIPT active mechanoresponsive luminescent AIEgen and its on-off-on emissive response to Cu²⁺/S^2-,
B. Tharmalingam, M.  Mathivanan, G. Dhamodiran, K.S. Mani, M. Paranjothy and B. Murugesapandian*
ACS Omega, 4, 12459-12469 (2019).

19. Coumarin based hydrazone as an ICT-based fluorescence chemosensor for the detection of Cu²⁺ ions and the application in HeLa cells,
K.S. Mani, R. Rajamanikandan, B. Murugesapandian, R. Shankar, G.  Sivaraman, M. Ilanchelian, S. P. Rajendran,
Spectrochim. Acta A: Mol. and Biomol. Spectrosc., 214, 170-176 (2019).

20. D–A–D structured bis-acylhydrazoneexhibiting aggregation-induced emission, mechanochromicluminescence, and Al (III) detection,
K. Santhiya, S. K.Sen, R.  Natarajan, R. Shankar and B. Murugesapandian*
J. Org. Chem., 83, 10770-10775 (2018).

21. Enantioselective approach towards the synthesis of spiroindeno [1,2-b] quinoxalinepyrrolothiazoles as antioxidant and antiproliferative,
K. S. Mani, B. Murugesapandian, W. Kaminsky, S. P. Rajendran,
Tetrahedron Lett., 59, 2921-2929 (2018).

22. Cerium complex-catalyzed oxidation of arylmethanols under atmospheric pressure of dioxygen and its mechanism through a side-on μ-peroxodicerium(IV) Complex.
M. Paul, S. Shirase, Y. Morimoto, L. Mathey, B. Murugesapandian, S. Tanaka, S. Itoh, H. Tsurugi, H. K. Mashima,
Chem. Eur. J., 22, 4008–4014 (2016).

23. Dihaloboreniumcations stabilized by a four membered N-heterocyclic carbene: electron deficiency compensation by asymmetric structural changes.
M.Q.Y. Tay, B. Murugesapandian, Y. Lu, R. Ganguly, K. Rei, and D. Vidović,
Dalton Trans., 43, 15313-15316 (2014).

24. {CH₂(PPh₂NSi-Me₃)(Ph₂PS)} and {CH(PPh₂NSi-Me¬)(Ph₂PS)}- as a ligand in zinc chemistry- synthesis and structures,
M. Kuzdrowska, B. Murugesapandian, L. Hartenstein, M. T. Gamer, N. Arleth, S. Blechert, and P. W. Roesky,
Eur. J. Inorg. Chem., 4851-4857 (2013).

25. (Iminophosphoranyl)(thiophosphoranyl)methanide{CH(PPh₂NSi-Me¬)(Ph₂PS)}-as a ligand in rare-earth-element chemistry,
B. Murugesapandian, M. Kuzdrowska, M. T. Gamer, L. Hartenstein and P.W. Roesky, Organometallics, 32, 1500-1506 (2013)

26. A phosphorus-based compartmental ligand, (S)P[N(Me)N=CH-C₆H₃-2-O-3-OMe]₃ (LH₃), enables the assembly of  luminescent heterobimetalliclinear {L2Zn2Ln}+ [Ln = Gd, Tb, Nd and Eu]  complexes,
V. Chandrasekhar, P. Bag, B.Murugesapandian,and M. D. Pandey,
Dalton Trans., 42, 15447-15456 (2013)

27. Synthesis and structure of lead(II) complexes of [(ƞ⁶-benzenecarboxylato)tricarbonylchromium.
B. Murugesapandian and P. W. Roesky,
Eur. J. Inorg. Chem., 292-297 (2012).

28. Synthesis and Structure of Zinc(II) and Cadmium(II) Complexes with [(ƞ⁶-Benzenecarboxylate) Chromium Tricarbonlyl and Pyrazole Derivatives,
B. Murugesapandian and P. W. Roesky,
Z. anorg. allg. Chem., 637, 1818-1823 (2011).

29. Hydrogen bonding networks in [(η⁶-arene)Cr(CO)₃] complexes,
B. Murugesapandian and P. W. Roesky,
Heteroat. Chem., 22, 294-300 (2011).

30.  Synthesis and Structure of Cadmium(II) complexes with (ƞ⁶-benzenecarboxylate)tricarbonylchromium,
B. Murugesapandian and P. W. Roesky,
Eur. J. Inorg. Chem., 4103-4108 (2011).

31. Coordination Polymers of Zinc with [(ƞ⁶-benzenecarboxylate) Chromium Tricarbonyl,
B. Murugesapandian and P. W. Roesky,
Inorg. Chem., 50 (5) 1698-1704 (2011).

32. Synthesis, Structure, rand Two-Photon Absorption Studies of a Phosphorus-Based TrisHydrazone Ligand (S)P[N(Me)N=CH-C₆H₃-2-OH-4-N(CH₂CH₃)₂]₃ and Its Metal Complexes,
V. Chandrasekhar, R. Azhakar, B. Murugesapandian, T. Senapati, P. Bag, M. D. Pandey, S. K. Maurya and D. Goswami.
Inorg. Chem., 49 (9), 4008–4016 (2010).

33. Sodium and Potassium Compounds of [(ƞ⁶-benzenecarboxylate)Cr(CO)₃] and [(ƞ⁶-1,4-benzenedicarboxylate)-Cr(CO)₃],
B. Murugesapandianand P. W. Roesky,
Dalton Trans., 39, 9598-9603 (2010).

34. Phosphorus-Supported Ligands for the Assembly of Multimetal Architectures,
V. Chandrasekhar and B. Murugesapandian,
Acc. Chem. Res., 42 (8), 1047–1062 (2009).

35. Synthesis, Structure, and Magnetism of HeterobimetallicTrinuclear Complexes {[L₂Co₂Ln][X]} [Ln = Eu, X = Cl; Ln = Tb, Dy, Ho, X = NO₃; LH₃ = (S)P[N(Me)N=CH−C₆H₃-2-OH-3-OMe]₃]: A 3d−4f Family of Single-Molecule Magnets,
V. Chandrasekhar, B. MurugesaPandian, J. J. Vittal and R. Clérac,
Inorg. Chem., 48 (3), 1148–1157 (2009).

36. TrinuclearHeterobimetallic Ni₂Ln complexes [L₂Ni₂Ln][ClO4] (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er; LH₃ = (S)P[N(Me)N=CH−C₆H₃-2-OH-3-OMe]₃): From Simple Paramagnetic Complexes to Single-Molecule Magnet Behavior,
V. Chandrasekhar, B. MurugesaPandian, R. Boomishankar, A. Steiner, J. J. Vittal and R. Clérac,
Inorg. Chem., 47(11), 4918-4929 (2008).

37. A Tunable Coordination Response of the Phosphorus-Based Hexadentate Ligand (S)P[N(Me)N=CHC₆H₄-o-OH]₃ (LH₃): Synthesis and Structure of LM (M = Sc, Cr, Mn, Fe, Co, Ga),
V. Chandrasekhar, R. Azhakar, B. MurugesaPandian, J. F. Bickley and A. Steiner,
Eur. J. Inorg. Chem., 7, 1116-1124 (2008).

38. Cyclophosphazene-Supported Tetranuclear Copper Assembly Containing 15 Contiguous Inorganic Rings,
V. Chandrasekhar, G. T. SenthilAndavan, R. Azhakar and B. MurugesaPandian,
Inorg. Chem., 47 (6), 1922–1924 (2008).

39. Synthesis, structure and metallation of spiro-N₃P₃(O₂C₁₂H₈)(OC₅H₄N-2)₄: A heptacoordinate Co(II) in the molecular structure of N₃P₃(O₂C₁₂H₈)(OC₅H₄N-2)₄•Co(NO₃)₂,
V. Chandrasekhar, B. MurugesaPandianand R. Azhakar,
Polyhedron, 27, 255-262 (2008).

40.    A phosphorus-supported multisite coordination ligand containing three imidazolyl arms and its metalationbehaviour. An unprecedented co-existence of mononuclear and macrocyclicdinuclear Zn(II) complexes in the same unit cell of a crystalline lattice,
V. Chandrasekhar, R. Azhakar, B. MurugesaPandian, R. Boomishankar and A. Steiner,
Dalton Trans., 43, 5962-5969 (2008).

41. Synthesis, structure and magnetic properties of linear heterobimetallictrinuclear Mn₂Ln (Ln = Eu, Gd, Dy) complexes,
V. Chandrasekhar, B. MurugesaPandian, R. Boomishankar, A. Steiner and R. Clérac,
Dalton Trans., 38, 5143-5145 (2008).

42. 42- and 46-Membered Phosphorus-Based Macrocycles,
V. Chandrasekhar, G. T. SenthilAndavan, R. Azhakar and B. MurugesaPandian,
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 37, 725-728 (2007).

43. Linear Trinuclear Mixed-Metal CoII−GdIII−CoII Single-Molecule Magnet:  [L₂Co₂Gd][NO₃]•2CHCl₃ (LH3 =(S)P[N(Me)NCH−C₆H₃-2-OH-3-OMe]₃),
V. Chandrasekhar, B. MurugesaPandian, R. Azhakar, J. J. Vittal and R. Clérac,
Inorg. Chem. 46 (13), 5140–5142 (2007).

44. Cyclophosphazene-based multi-site coordination ligands,
V. Chandrasekhar, P. Thilagar and B. MurugesaPandian,
Coord. Chem. Rev., 251, 1045-1074 (2007).

45. 36- and 42-Membered cyclophosphazene-containing macro-cycles,
V. Chandrasekhar, G. T. SenthilAndavan, R. Azhakar and B. MurugesaPandian,
Tetrahedron Lett., 47, 8365-8368 (2006).

46. Cyclocarbophosphazene-Containing Tetrameric Assemblies Formed by the Mediation of P−O−P and P−O−Cu Linkages,
V. Chandrasekhar, R. Azhakar, V. Krishnan, A. Athimoolam and B. MurugesaPandian,
J. Am. Chem. Soc.,128 (21), 6802–6803 (2006).

47. Di- and Trinuclear Complexes Derived from Hexakis(2-pyridyloxy)cyclotriphosphazene. Unusual P−O Bond Cleavage in the Formation of [{(L‘CuCl)₂(Co(NO₃)}Cl] (L‘ = N₃P₃(OC₅H₄N)₅(O)),
V. Chandrasekhar, B. MurugesaPandianand R. Azhakar,
Inorg. Chem. 45 (9), 3510–3518 (2006)
 

Ongoing

Candidate Name: K. Suganthirani

Date of Registration: November 2017

 

Candidate Name:  Aiswarya Janardhanan 

Date of Registration: January 2021

 

Candidate Name: R. Kishore Kumar

Date of Registration: January 2022

Completed

Candidate Name: K. Santhiya

Title of Thesis : "Functional Fluorescent Organic Materials: Design, Synthesis, Optical Properties and Sensing Applications" 

Year of Award: 2020

 

Candidate Name: B. Tharmalingam

Title of Thesis : "Star-shaped Triaminoguanidine as Scaffold for the Construction of Hydrazone Based Multi-Functional Materials and Its Sensing Application" 

Year of Award: 2021

 

Candidate Name: M. Mathivanan

Title of Thesis : "Design, Development and Sensing Applications of Triphenylamine and 7-Diethylamino-4-hydroxycoumarin Based Multi-Functional Material"

Year of Award: 2021

 

Candidate Name: O Anitha

Title of Thesis : "Pyrimidine bis hydrazone derivatives: Design, Synthesis, Optical properties, Stimuli responsiveness, sensing and Coordination features"

Date of Registration: January 2021(thesis submitted on October 2023)